A study Cu (Ⅱ) Extraction from wastewater by Ionic Liquid Aliquat 336 under assistance. EDTA

Bin Hang

Abstract


Under the assistance of EDTA, the extraction property of hydrogen ionic liquid aliquat 336 (methyl trout ammonium chloride) on Cu (II) Was studied. The results showold that, when the volume ratio of aliquat 336 to aqueous solution was 1:5.,The initial mass concentration of Cu (II) Was 600 mg/L, the pH value was 4, adding equilibrium EDTA could enable the extraction rate of Cu (II) From 5.0% to 88.7%, which indicated that, the presence of completing agent EDTA could significantly improved the extraction rate of Cu (II) In the simulated water. The optimal extraction condition was as follows: the mass ratio of EDTA to Cu (II) Was 1.0, the value of VIls:VAQWas 1:5, the pH value was 4, the temperature was 25. Under the above referral-tion, the removal rate of Cu (II) From the water recovered 88.7%. aliquat 336 can be recycled for many times, the extraction rate still remains above 80% even it has been reclaimed for 4 times.


Keywords


Aliquat 336; ionic liquid extraction; Cu(II); Completing agent


Included Database


References


Kang little redYang cloudragon.Magnetic flocculation removal Industrial Wastewater in copper ion of TestStudyJ. .Industrial Water and Wastewater201142(3):24-27.

RajendranRagupathy DPriyadarshini MEt al.Effective extraction. heavy metals. effluents using some Potential ionic liquids as green chemicalsJ. .E-Journal. Chemistry20118(2):697-702.

EROSA M S DMEDINA T I SMENDOZA R NEt al.Partex sorption. chitosan sorbents:Kinetic, Equilibrium studiesJ. .Hydrometallurgy200161(3):157-167.

Pei shi hongThank you RuiliJin mengSuch..Wet copper commonly used of copper ExtractantJ. .When S chemical200938(1):78-82.

Paper your honorDu Tiger.Cobalt wastewater processing methods and Its Research ProgressJ. .Industrial water And Wastewater201445(5):5-9.

EARLE M JSEDDON K R.Ionic liquids-Green solvents. futureJ. .Pure, Applied Chemistry200072(7/):1391-1398.

ROGERS R DSEDDON K R.Ionic liquids:Solvents.Future? J. .Science2003302(5646):792-793.

Zhang YanZhao its YangBed yao haiSuch..Temperature Control-assisted ionic liquid dispersion-Liquid micro-Extraction-High performance liquid chromatography detection juice in fungicides residualJ. .Food Science201536(4):202-207.

L KMa w wZhang d xEt al.Ultra-Sound-Icg-eac Liquid-Liquid microextraction based. an ionic liquid. preconcen-tration, determination UV filters. environmental Water

ZHOU Q XGAO Y.Combined transport bill of. ionic liquid dispersive Liquid-Phase microextraction. performance liquid chromato-graphy. determination. triazine herbicides. Water SamplesJ. .Chin Chem Lett201425(5):745-748.

Abolhasani JAmjadi MKalhoreg.Ultra-Trace deter-mination. Copper, silver. environmental Samples by using ionic liquid-Based Single Drop microex-Traction-Electrothermal Atomic absorption spectrometryJ. .Joural. Chemical Health risks20133(3):631-640.

HAMID SKAVEH SHassan twig u & Z M.Determination. traceLead. industrial municipal effluent water samples based. dispersive Liquid-Liquid ExtractionJ. .J Mex SOC,2014,58(2.):137-141.

Gong Xuan,Chen Mindong.Research Progress of ionic liquids in extraction of metalsExhibitionJ. .Chemical Reagent,2012,34(1.):41-47

Lertlapwasin R,Bhawaii n,Imyim,Et al.Ionic Liquid Extraction of Heavy Metal Ions by 2-Aminothiophenol in 1-Butyl-3.-Methymidazolium hexafluorophosphate and their assoccia-tion ConstantsJ. .Separation&Purification Technology,2010,72(1.):70-76.

Li J F,Li E Z,Du Z P,Et al. facile generation of Rod-Like PbCl2.Crystals from Pb(II)Aqueous Solutions induced by aliquat 336 AT ROOM TEMPERATUREJ. .Journal of chemical technology and biotechnology,2017,Doi:10.1002/Jctb.5250.

Li Changping,Xin Baoping,Xu wenguo,Wait..Hydrophobic ionic liquids as solvent PairsCO2.+AndCD2.+Extraction performance of WastewaterJ. .Journal of Process Engineering,2007,7.(4.):674-678.

Wang Far East.Viscosity and Impedance Characteristics of Ionic Liquids and Their Analytical ApplicationD. .JiSouth:Shandong Normal University,2008.

Liu Junan,Zhang Qian,Ren Xiaowen,Wait..Hydrophobic Ionic LiquidsCu2.+Study on Extraction performance of WastewaterJ. .Journal of CentralChina Normal University(From the Ke version),2010,44(1.):80-85.


Refbacks

  • There are currently no refbacks.